Coming from someone who doesn't like to invest a ton of time in TV...
My wife will watch much more than I do, and she knows if it's something I may have an interest in. I've abandoned more series than I care to count after one episode, because I can't sit through it if my mind goes somewhere else.
Anyway, top 4 in this order:
The Wire
Breaking Bad
Arrested Development
Deadwood
I'll throw in an honorable mention for the recent Sherlock Holmes series done by the BBC starring Benedict Cumberbatch, these are really well done.