Check the AGP Graphics Aperature Size
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Stardock Forums
GalCiv was constantly freezing on my computer until I went into the BIOS to check my AGP Graphics Aperature Size. I had recently bought a Nvidia Ti4200 with 128 megs of RAM but forgot to change the Aperature Size in my BIOS. It was set to 32 megs but I changed it to 128 megs and now the game hasn't froze since then. I thought I might pass this along for the purpose of helping people with the same problem. It worked for me.
~SDC~
~SDC~